"It should be noted that octane rating does not relate to the energy content of the fuel (see heating value), nor the speed at which the flame initiated by the spark plug propagates across the cylinder. It is only a measure of the fuel's resistance to autoignition. It is for this reason that one highly branched form, or isomer, of octane (2,2,4-trimethylpentane) has (by definition) an octane rating of 100, whereas n-octane (see octane), which has a linear arrangement of the 8 carbon atoms, has an octane rating of -10, even though the two fuels have exactly the same chemical formula and virtually identical heating values and flame speeds."

"Under ideal conditions the common piston internal combustion engine burns its fuel/air mix in the cylinder in an orderly and controlled fashion. The combustion is started by the spark plug some 5 to 40 crankshaft degrees prior to top dead center (TDC), depending on engine speed and load. This ignition advance allows time for the combustion process to develop peak pressure at the ideal time for maximum recovery of work from the expanding gases.
The spark across the spark plug's electrodes forms a small kernel of flame approximately the size of the spark plug gap. As it grows in size its heat output increases allowing it to grow at an accelerating rate, expanding rapidly through the combustion chamber. This growth is due to the travel of the flame front through the combustible fuel air mix itself and due to turbulence rapidly stretching the burning zone into a complex of fingers of burning fuel air that have a much greater surface area than a simple spherical ball of flame would have. In normal combustion, this flame front moves throughout the fuel air mix at a rate characteristic for the fuel-air mixture. Pressure rises smoothly to a peak, as nearly all the available fuel is consumed, then pressure falls as the piston descends. Maximum cylinder pressure is achieved a few crankshaft degrees after the piston passes TDC, so that the increasing pressure can give the piston a hard push when its speed and mechanical advantage on the crank shaft gives the best recovery of force from the expanding gases."